To draw a reaction query:
Open the Structure Drawing window by clicking on the Prepare Query button on the Main Menu Toolbar or selecting Prepare Structure Query from the Query menu.
Click the Reaction (Rxn) button on the Structure Drawing Toolbar or select Show Reactions from the Display menu. The Structure Drawing window is displayed in Reaction mode, and the Reaction Drawing tools are activated on the Tool Palette:
Reaction Arrow tool - to set up a chemical reaction between structures
Reaction Role tool - to specify the roles of the participants in a reaction
Reaction Site Tool - to specify a reaction site label for a specific bond
Atom Mapping Tool - to specify a correspondence between atoms in the reactant and atoms in the product
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